UC Riverside

Chlorate (ClO₃^-) is a common water pollutant due to its gigantic scale of production, wide applications in agriculture and industry, and formation as a toxic byproduct in various water treatment processes. This work reports on the facile preparation, mechanistic elucidation, and kinetic evaluation of a bimetallic catalyst for highly active ClO₃^- reduction into Cl^-. Under 1 atm H₂ and 20 °C, Pd^II and Ru^III were sequentially adsorbed and reduced on a powdered activated carbon support, affording Ru⁰-Pd⁰/C from scratch within only 20 min. The Pd⁰ particles significantly accelerated the reductive immobilization of Ru^III as >55% dispersed Ru⁰ outside Pd⁰. At pH 7, Ru-Pd/C shows a substantially higher activity of ClO₃^- reduction (initial turnover frequency >13.9 min^-1 on Ru⁰; rate constant at 4050 L h^-1 g_metal^-1) than reported catalysts (e.g., Rh/C, Ir/C, Mo-Pd/C) and the monometallic Ru/C. In particular, Ru-Pd/C accomplished the reduction of concentrated 100 mM ClO₃^- (turnover number > 11,970), whereas Ru/C was quickly deactivated. In the bimetallic synergy, Ru⁰ rapidly reduces ClO₃^- while Pd⁰ scavenges the Ru-passivating ClO₂^- and restores Ru⁰. This work demonstrates a simple and effective design for heterogeneous catalysts tailored for emerging water treatment needs.